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Intern Info Alison Norton Identification of voruscharin biosynthetic genes through differential gene expression analysis of Asclepias species Cardiac glycosides are secondary metabolites produced in plants as toxic defenses against herbivorous insects

Its enzymatic function is based on two aspects: its catalytic activity and the auto- S -glutathionylation of GST by itself on Cys47 and Cys10, both of which disturb the subsequent interaction with c-Jun NH 2 -terminal kinase (JNK), resulting in the formation of a GST multimer 30 (Figure 3)

therefore you can see that a vicious cycle exists

Green RM, Graham M, O'Donovan MR, Chipman JK, Hodges NJ (2006) Subcellular compartmentalization of glutathione: correlations with parameters of oxidative stress related to genotoxicity